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101.
Bohao Cheng Zhijie Zhang Xiaowen Wu Xin Min Zhaohui Huang Tianyi Tao Haiqing Zhao Minghao Fang Yan-gai Liu 《International Journal of Applied Ceramic Technology》2019,16(1):69-76
The ZrN-SiAlON composite powder was synthesized using low-grade zircon and bauxite by carbothermal reduction nitridation at first and then ZrN-SiAlON-SiC-C composite refractory were fabricated with the ZrN-SiAlON powder, SiC particles, and a small amount of Si powder as raw materials and sucrose as the binder. The slag resistance of these composites in O2, N2 and Ar atmosphere was investigated by X-ray diffraction, scanning electron microscopy, and energy dispersion spectra. The results show that the pores in the inside of ZrN-SiAlON-SiC-C composite refractory were enlarged in oxygen atmosphere due to oxidation, which leads to the decrease in slag resistance. In argon atmosphere, blast furnace slag destroyed the sintered body of zircon, corundum, and cristobalite with the formation of CaZrO3, then infiltrated into and filled the pores inside the refractory to form a dense layer, which hindered the further erosion of the blast furnace slag. In the reducing atmosphere, the interfacial energy of the gas-liquid phases became larger due to the reactions between blast furnace slag liquid and the gas, resulting in a larger wetting angle which prevented the erosion. 相似文献
102.
Chen Gang Liss Klaus-Dieter Cao Peng Lu Xin Qu Xuanhui 《Metallurgical and Materials Transactions B》2019,50(1):429-437
Metallurgical and Materials Transactions B - Sintering behaviors of two types of powder compact, i.e., Ti/Al and TiH2/Al, under vacuum were studied using in situ neutron diffraction, in situ... 相似文献
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Yifan Zhang Shaowei Bo Tao Feng Xialing Qin Yilin Wan Shanshan Jiang Chunxiao Li Jing Lin Tianfu Wang Xin Zhou Zhong‐Xing Jiang Peng Huang 《Advanced materials (Deerfield Beach, Fla.)》2019,31(21)
To design a clinically translatable nanomedicine for photodynamic theranostics, the ingredients should be carefully considered. A high content of nanocarriers may cause extra toxicity in metabolism, and multiple theranostic agents would complicate the preparation process. These issues would be of less concern if the nanocarrier itself has most of the theranostic functions. In this work, a poly(ethylene glycol)‐boron dipyrromethene amphiphile (PEG‐F54‐BODIPY) with 54 fluorine‐19 (19F) is synthesized and employed to emulsify perfluorohexane (PFH) into a theranostic nanoemulsion (PFH@PEG‐F54‐BODIPY). The as‐prepared PFH@PEG‐F54‐BODIPY can perform architecture‐dependent fluorescence/photoacoustic/19F magnetic resonance multimodal imaging, providing more information about the in vivo structure evolution of nanomedicine. Importantly, this nanoemulsion significantly enhances the therapeutic effect of BODIPY through both the high oxygen dissolving capability and less self‐quenching of BODIPY molecules. More interestingly, PFH@PEG‐F54‐BODIPY shows high level of tumor accumulation and long tumor retention time, allowing a repeated light irradiation after a single‐dose intravenous injection. The “all‐in‐one” photodynamic theranostic nanoemulsion has simple composition, remarkable theranostic efficacy, and novel treatment pattern, and thus presents an intriguing avenue to developing clinically translatable theranostic agents. 相似文献
105.
Ting Hui Yuan Zhen Hua Zhang Jin Li Da Quan Zhang Li Xin Gao Wen Ge Li Zhi Feng Fan 《工业材料与腐蚀》2019,70(7):1298-1305
In the study, polyaniline/reduced‐graphene oxide (PANI‐RGO) composites, fabricated by loading 2, 5, and 8wt% graphene oxide, was prepared by in‐situ emulsion polymerization and reduction. They are characterized by Fourier transform infrared spectroscopy, X‐ray diffraction, and scanning electron microscopy. Epoxy coatings adding PANI and PANI‐RGO composites were coated on the surface of AA5083 Al alloy. The anticorrosion performance of the coatings is measured by electrochemical impedance spectroscopy and potentiodynamic polarization curve in 3.5wt% NaCl solution. The results demonstrate that the epoxy/PANI‐RGO coating exhibits a better protection against AA5083 alloy corrosion compared with the epoxy/PANI coating. Enhancement of the passivation performance of PANI was obtained by the addition of RGO into epoxy/PANI coating system. 相似文献
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以超临界二氧化碳干气密封为研究对象,分别以维里方程、Lucas方程描述二氧化碳真实气体效应、黏度的变化,在考虑阻塞流效应的同时,采用有限差分法对考虑离心惯性力效应的Reynolds方程与能量控制方程进行耦合求解,分析讨论了工况参数与槽形结构参数对其相态分布规律与密封性能的影响。研究表明:S-CO2从密封端面进口至出口的流动过程中,如果工况参数设置合理,将由超临界态逐渐转变为气态,并不会出现液态;较低的进口压力、进口温度以及转速,均会容易导致潜在的凝结流动发生;相比于工况参数对相态分布的影响,槽形参数对相态分布的影响较小,近乎可以忽略;开启力除了随进口温度的升高而减小外,均随进口压力、转速、槽深、螺旋角的增大而增大;泄漏率随进口温度和转速的增大而减小,但其随进口压力、槽深、螺旋角的增大而增大。这些结果为进一步研究超临界二氧化碳干气密封提供了一定的支撑。 相似文献
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